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On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes

Part of the Springer Theses Book Series

DOI: 10.1007/978-3-319-51807-7

ISBN: 978-3-319-51806-0

Publisher: Springer International Publishing - Springer Journals

Feb 15, 2017

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Chapter 1General Introduction

Hadlington, Terrance John

Pages: 1 –12

[Contrary to the wide ranging nature of d- and f-block chemistry, that of the s- and p-block elements has classically been accepted as limited to one or two stable oxidation states outside of the elemental species, thus curtailing the broader reactivity of compounds involving these elements....
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Chapter 2The Development of Extremely Bulky Amide Ligands and Their Application to the Synthesis of Group 14 Element(II) Halide Complexes

Hadlington, Terrance John

Pages: 13 –42

[As described in Chap. 1, the isolation of some of the first examples of low-oxidation state main-group (MG) complexes has involved the use of sterically demanding and poly-dentate ligand systems, which kinetically stabilise reactive element centres. Two main classes of mono-anionic ligand have...
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Chapter 3Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands

Hadlington, Terrance John

Pages: 43 –112

[Over recent decades, numerous landmark discoveries in the area of main-group chemistry have been realised. Of most relevance to this thesis are the advances that have been made in regards to complexes incorporating the heavier group 14 elements in unusual co-ordination environments and oxidation...
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Chapter 4Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes

Hadlington, Terrance John

Pages: 113 –145

[The addition of element-hydrogen bonds across unsaturations (i.e. hydroelementation) is of paramount importance in organic synthesis. The application of group 14 element-hydrogen (E–H) bonds in this regard, however, has largely relied upon transition-metal (TM) catalysts or radical mechanisms....
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Chapter 5Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrylene Derivatives

Hadlington, Terrance John

Pages: 147 –203

[Whilst the spotlight has been on the synthesis and reactivity of the heavier alkyne analogues (LEEL, E = Si–Pb) in regards to low-oxidation state group 14 chemistry, the reactivity of heavier carbene analogues (L2E:) has also seen considerable interest. Specifically, small-molecule activation in...
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Chapter 6The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry

Hadlington, Terrance John

Pages: 205 –237

[This chapter describes the synthesis and application of a novel boryl silyl amide ligand in low-oxidation state, low-coordinate group 14 chemistry. This is, in part, related to chmistry discussed in previous chapters: the synthesis of group 14 halide complexes using monodentate ligands (Chap....

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