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Assemblies of Gold Nanoparticles at Liquid-Liquid Interfaces

Part of the Springer Theses Book Series

DOI: 10.1007/978-3-319-77914-0

ISBN: 978-3-319-77913-3

Publisher: Springer International Publishing - Springer Journals

Apr 20, 2018

1 - 9 of 9 Chapters

LitStream

Chapter 1Introduction

Smirnov, Evgeny

Pages: 1 –63

[This Chapter contains general introduction to electrochemistry at ITIES, including interfacial structure and thermodynamics of electron and ion transfer, as well as description of the concept of the Fermi level equilibration. Next, synthetic procedures, the structure of citrate-stabilized gold...
LitStream

Chapter 2Experimental and Instrumentation

Smirnov, Evgeny

Pages: 65 –85

[This Chapter is fully devoted to experimental procedures, to synthesize and analyze assemblies of nanoparticles and to instrumentation techniques used in this work.]
LitStream

Chapter 3Self-Assembly of Nanoparticles into Gold Metal Liquid-like Droplets (MeLLDs)

Smirnov, Evgeny

Pages: 87 –117

[Simple methods to self-assemble coatings and films from nanoparticles are highly desirable in many practical scenarios, yet scarcely any examples of simple, robust approaches to coat macroscopic droplets with continuous, thick (multilayer), reflective, and stable liquid nanoparticle films exist....
LitStream

Chapter 4Optical Properties of Self-healing Gold Nanoparticles Mirrors and Filters at Liquid–Liquid Interfaces

Smirnov, Evgeny

Pages: 119 –143

[This chapter illustrates a detailed study of optical and morphological properties of lustrous self-healing metal liquid-like nanofilms for different applications (e.g., optical mirrors or filters). Extinction and reflectance of nanofilms were investigated by an integrating sphere in UV, visible...
LitStream

Chapter 5Self-Assembly of Gold Nanoparticles: Low Interfacial Tensions

Smirnov, Evgeny

Pages: 145 –155

[In this chapter, we would highlight the critical role of the interfacial tension and three-phase contact angle in self-assembly process of gold nanoparticles at a liquid–liquid interface. We demonstrate that gold nanoparticles can spontaneously self-assemble at bare propylene carbonate–water...
LitStream

Chapter 6Electrochemical Investigation of Nanofilms at Liquid–Liquid Interface

Smirnov, Evgeny

Pages: 157 –172

[Soft or “liquid–liquid” interfaces were functionalized by roughly half a monolayer of mirror-like nanofilms of gold nanoparticles using a precise interfacial microinjection method. The surface coverage of the nanofilm was characterized by ion-transfer voltammetry. These gold nanoparticle films...
LitStream

Chapter 7Electron Transfer Reactions and Redox Catalysis on Gold Nanofilms at Soft Interfaces

Smirnov, Evgeny

Pages: 173 –197

[The dispute about the exact and correct mechanism of the electron transfer (ET) reactions at liquid–liquid interfaces has lasted for decades. The ET reaction at ITIES was studied experimentally and by computer simulations for a model system. This model system contains...
LitStream

Chapter 8Gold Nanofilm Redox Electrocatalysis for Oxygen Reduction at Soft Interfaces

Smirnov, Evgeny

Pages: 199 –220

[The interfacial reduction of oxygen by a lipophilic electron donor, decamethylferrocene, dissolved in α,α,α-trifluorotoluene was catalyzed at a gold nanoparticle nanofilm modified water–oil interface. A recently developed microinjection technique was utilized to modify the interface reproducibly...
LitStream

Chapter 9Perspectives: From Colloidosomes Through SERS to Electrically Driven Marangoni Shutters

Smirnov, Evgeny

Pages: 221 –256

[This Chapter highlights the perspectives to realize the potential of MeLLD-type gold nanoparticle films at liquid-liquid interface. Among them are: microencapsulation for drug-delivery systems and microreactors; transfer of nanofilms from LLI to a solid interface for reusable SERS-substrates and...

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