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Visualization of Hydrogen-Bond Dynamics

Part of the Springer Theses Book Series (volume 125)

DOI: 10.1007/978-4-431-54156-1

ISBN: 978-4-431-54155-4

Publisher: Springer Japan - Springer Journals

Sep 2, 2012

1 - 10 of 11 Chapters

LitStream

Chapter 1Introduction

Kumagai, Takashi

Pages: 1 –10

[The main topic of this thesis is visualization of H-bond dynamics within water-based model systems assembled on a metal surface. Scanning tunneling microscope (STM) is employed to image and engineer such model systems at the single molecule level. H-bond dynamics of water molecules, i.e., the...
LitStream

Chapter 2Principles and Techniques

Kumagai, Takashi

Pages: 11 –31

[I describe a brief summary of quantum mechanics and principles of scanning tunneling microscopy (STM) in this chapter. Quantum tunneling is an important concept to describe the transportation of small particles, like electron and hydrogen. In Sect. 2.1 I focus on H-atom tunneling in a double...
LitStream

Chapter 3Experiments

Kumagai, Takashi

Pages: 33 –41

[I describe experimental details in this chapter. All experiments were conducted under ultra-high vacuum (UHV) conditions. In general, since single-crystalline surfaces of semiconductor and metal are very reactive, they are readily contaminated by H2O, O2, etc. in atmospheric conditions....
LitStream

Chapter 4Water Monomer: Structure and Diffusion of a Single Water Molecule

Kumagai, Takashi

Pages: 43 –52

[I describe the structure and diffusion of a single water molecule isolated on a Cu(110) surface in this chapter. The monomeric adsorption of water molecules can be realized at low temperature (<20 K). The adsorption structure is determined with the help of DFT calculations. A water molecule...
LitStream

Chapter 5Water Dimer: Direct Observation of Hydrogen-Bond Exchange

Kumagai, Takashi

Pages: 53 –65

[I describe the direct observation of H-bond exchange reaction within a water dimer isolated on a Cu(110) surface in this chapter. A water dimer consisted of H-bond donor and acceptor molecule can be produced by the association of water monomers. The STM image of a dimer is characterized by an...
LitStream

Chapter 6Water Clusters: Formation of One-Dimensional Water Clusters

Kumagai, Takashi

Pages: 67 –78

[I describe the assembly and characterization of small water clusters on a Cu(110) surface in this chapter. One-dimensional (1-D) chain-like clusters (3–6 molecules), where water molecules are arranged along the Cu row to form a “ferroelectric” zigzag configuration, are assembled in a fully...
LitStream

Chapter 7Hydroxyl Group: Tunneling Dynamics of Hydrogen Atom

Kumagai, Takashi

Pages: 79 –90

[I describe the production and characterization of isolated hydroxyl species on a Cu(110) surface in this chapter. A hydroxyl group can be produced by the STM-induced dissociation of a water molecule. A hydroxyl can be further dissociated into atomic oxygen. It is found that a hydroxyl has an...
LitStream

Chapter 8Hydroxyl Dimer: Non-linear I–V Characteristics in an STM Junction

Kumagai, Takashi

Pages: 91 –100

[I describe the assembly and characterization of a hydroxyl dimer on a Cu(110) surface in this chapter. A dimer is produced by the reaction between a water and atomic oxygen with the STM manipulation. Hydroxyl groups in a dimer have an inclined geometry in common with a monomer and flips back and...
LitStream

Chapter 9Water-Hydroxyl Complexes: Direct Observation of a Symmetric Hydrogen Bond

Kumagai, Takashi

Pages: 101 –113

[I describe the hydration of a hydroxyl group with a water molecule on a Cu(110) surface and the characterization of water-hydroxyl complexes in this chapter. Two different structural isomers are selectively produced depending on the initial geometry of the reactants before the reaction. These...
LitStream

Chapter 10One-Dimensional Water-Hydroxyl Chain Complexes: Hydrogen-Atom Relay Reactions in Real Space

Kumagai, Takashi

Pages: 115 –130

[In this chapter I describe the real-space observation of H-atom relay reactions in one-dimensional (1-D) water-hydroxyl complexes where a water and hydroxyl molecules interact via H bond and are aligned along the [001] direction on a Cu(110) surface. The 1-D chain-like complexes, represented by...

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