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Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation

Part of the Springer Theses Book Series

DOI: 10.1007/978-4-431-54928-4

ISBN: 978-4-431-54927-7

Publisher: Springer Japan - Springer Journals

Jul 8, 2014

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Chapter 1General Introduction

Matsumoto, Arimasa

Pages: 1 –9

[Chapter 1 describes the importance of ubiquitous metals such as iron for sustainable catalysis, iron-catalyzed C–H bond activation reactions, and the synthesis of fused aromatic compounds via C–H bond activation. The development of iron-catalyzed reactions for the synthesis of fused aromatic...
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Chapter 2Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent

Matsumoto, Arimasa

Pages: 11 –22

[Linear fused acenes are important structures for organic semiconductors [1]. Naphthalene is the simplest acene and the [2+2+2] annulation reaction of an aromatic ring with two alkynes via C–H bond activation is an efficient method for synthesizing naphthalenes or other acene structures]
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Chapter 3Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent

Matsumoto, Arimasa

Pages: 23 –64

[In Chapter 3, a [4+2] benzannulation reaction of an alkyne with a biaryl Grignard reagent is described. The reaction of internal or terminal alkynes and phenyl Grignard reagent proceeded in the presence of catalytic amounts of an iron salt and a bipyridine-type ligand, with a dichloroalkane as...
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Chapter 4Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium

Matsumoto, Arimasa

Pages: 65 –71

[In the previous two chapters, iron-catalyzed synthesis of fused aromatics via C–H bond activation was developed. Although the reaction proceeds under mild conditions, the use of an unstable Grignard reagent is a practical disadvantage from the viewpoint of synthetic chemistry. Therefore, the...
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Chapter 5Summary and Perspectives

Matsumoto, Arimasa

Pages: 73 –74

[To achieve new reactivities of ubiquitous metals for the development of a sustainable society, the author investigated new reactions of organoiron species and developed an iron-catalyzed synthesis of naphthalene and phenanthrene derivatives.]

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