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Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes

Part of the Springer Theses Book Series

DOI: 10.1007/978-981-16-7148-7

ISBN: 978-981-16-7147-0

Publisher: Springer Singapore - Springer Journals

Nov 13, 2021

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Chapter 1General Introduction

Yamazaki, Yasuomi

Pages: 1 –6

[Light-induced electron and/or energy transfer are essential reactions for solar energy conversion, which is an urgent priority to achieve a sustainable society. In addition to the physicochemical research, synthetic chemistry for synthesizing various series of multifarious photofunctional...
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Chapter 2Synthesis of Multinuclear Complexes Using the Mizoroki–Heck Reaction

Yamazaki, Yasuomi

Pages: 7 –32

[An integration of photofunctional metal complexes is one of the useful strategies to develop multifarious photofunctional metal complexes. In particular, hetero-multinuclear complexes often show an enhancement in photoluminescent properties, photosensitizing abilities, and photocatalytic...
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Chapter 3Selective Synthesis of Various Photofunctional Multinuclear Complexes Using a Combination of the Mizoroki–Heck Reaction and the Homo-coupling Reaction

Yamazaki, Yasuomi

Pages: 33 –57

[As described in Chap. 2, the Mizoroki–Heck reaction between metal complexes with bromo groups and those with vinyl groups in the diimine ligand did not proceed using Pd(OAc)2 and a tertiary phosphine ligand under an Ar atmosphere. However, it proceeded selectively after the injection of air into...
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Chapter 4Photochemical and Electrochemical Hydrogenation of π-Conjugated Bridging Ligands on Photofunctional Multinuclear Complexes

Yamazaki, Yasuomi

Pages: 59 –84

[As described in Chaps. 2 and 3, a new class of multinuclear complexes, which have two photosensitizer units and a catalyst unit, was successfully synthesized by establishing the suitable reaction conditions for the Mizoroki–Heck reaction. However, the multinuclear complexes were linked through...
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Chapter 5Synthesis of Novel Multinuclear Complexes for Light-Harvesting Systems Using the Coupling Reactions with Ring-Shaped Multinuclear Re(I) Complexes as Building Blocks

Yamazaki, Yasuomi

Pages: 85 –102

[As described in Chap. 3, reaction conditions for the selective progress of the Mizoroki–Heck reaction and the homo-coupling reaction were successfully established. The coupling reactions are potentially applied for connecting with not only mononuclear complexes but also multinuclear complexes....
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Chapter 6Conclusions

Yamazaki, Yasuomi

Pages: 103 –104

[In this thesis, useful synthetic methods for multifarious multinuclear complexes, including the so-called “building block approach”, which utilizes various C–C coupling reactions between metal complexes with functional groups as active spots, were reported. The results are summarized as follows.]

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