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Even though chiral recognition for crown‐ether CSPs is generally understood, on a molecular level, exact mechanisms for the resolution are still unclear. Furthermore, short peptide analytes often contain multiple amino moieties capable of binding to the crown ether selector. In order to extend...
In this study, the hydrolysis of diclofop‐methyl (DM) in aqueous system and the bioaccumulation of its main metabolite, Diclofop (DA), in the tubifex worms were investigated using enantioselective high‐performance liquid chromatography. With the addition of tubifex, rapid hydrolysis was observed...
In this study, crown ether‐derived column Crownpak® CR‐I (+) was evaluated under SFC conditions using 12 primary amines, and the chromatographic results were compared against eight immobilized polysaccharide‐based columns. Crownpak® CR‐I (+) achieved a significantly higher success rate. It was...
Chiral heterocyclic alcohols are important precursors for production of pharmaceutical medicines and natural products. (S)‐1‐(furan‐2‐yl)propan‐1‐ol ((S)‐2) can be used production of pyranone, which can be used in the synthesis of sugar analogues, antibiotics, tirantamycines, and anticancer...
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