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The rare earth elements (REE) geochemistry and the isotope (δ13C, δ18O) composition of manganese ores of the Chiatura (Georgia) deposit were studied. One of the major features of all types of manganese ores is negative cerium (Ce/Ce*PAAS) anomaly and the absence of europium (Eu/Eu*PAAS) anomaly. Oxide oolitic manganese ores were formed in oxic shallow marine environments. The content and distribution of REEs (in particular Ce and Eu) in these ores are connected mainly with ferrous oxides. The performed C- and O-isotope research in Mn-carbonates (oolitic and massive) has indicated that carbonate ores were formed by the participation of isotopically light CO2 which is a result of the oxidation of organic matter in the sediment strata by reducing environments of early diagenesis (and, partially, catagenesis) zone. Obtained negative cerium anomalies in the studied carbonate ores reflect the specific REE patterns in pore waters of sediments of earlier isdiagenesis zone of the Oligocene Chiatura’s basin. The deficiency of cerium in this zone remains debatable and requires further study.Formation of manganese carbonates took place multistage by the input of incisional solutions of different chemistry into sea bottom waters and sediments. The absence of europium anomaly indicates about lack of hydrothermal solution input.
Acta Geochimica – Springer Journals
Published: Aug 1, 2023
Keywords: REE; Cerium anomaly; Carbon and oxygen isotope geochemistry; Oxide and carbonate manganese ores; Chiatura deposit
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